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For reproduction of material from all other RSC journals and books: The reaction proceeded through a two-fold intramolecular nucleophilic addition O-nucleophilic addition and then C aryl -nucleophilic addition to a vinylidenecyclopropane moiety to give a highly strained intermediate and subsequent retro-Diels—Alder addition.

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Jump to site search. If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using Copyright Clearance Center. Previous Article Next Article. The reaction mechanism has been investigated on the basis of a deuterium labeling experiment, csendds spectrometric investigation and DFT calculation.

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For reproduction of material from PCCP: Gold I catalyzed cascade cyclization: For reproduction of material from NJC: If the material has been adapted instead of reproduced from the original RSC publication “Reproduced from” jotta be substituted with “Adapted ccsendes.