DIENONE PHENOL REARRANGEMENT PDF
Re2O7 Catalyzed Dienone-Phenol Rearrangement. Zilei Xia,a,b,ǁ Jiadong Hu,a, b,ǁ Zhigao Shen,a,b Qizheng Yao*,a and Weiqing Xie*,b,c a Department of. Dienone–phenol rearrangement of 8,8-dimethyl- and 6,8,8-trimethyl-naphthalene -1,4,5(8H)-triones (1) and (2) in acetic anhydride as solvent is the subject of a. The experiment is based on the dienone-phenol rearrangement reaction of the sesquiterpene santonin to give -desmotroposantonin acetate. It challenges.
|Published (Last):||24 March 2004|
|PDF File Size:||17.67 Mb|
|ePub File Size:||14.79 Mb|
|Price:||Free* [*Free Regsitration Required]|
Fetching data from CrossRef. The results are rationalized in terms of the formation of acylated intermediate cations and schematic representation is provided. Dienone—phenol rearrangement mechanism of 8,8-dimethyl- and 6,8,8-trimethyl-naphthalene-1,4,5 8 H pjenol in acetic anhydride solution C. Back to tab navigation Download options Please wait Search articles by author Candelaria Goycoolea.
Reproduced material should be attributed as follows: For reproduction of material from all other RSC journals and books: Journal of the Chemical Society, Perkin Transactions 2. If you are the author of this article you still need to obtain permission to reproduce the whole article in a third party publication with the exception of reproduction of the whole article in a thesis or dissertation.
Previous Article Next Article. Dienone—phenol rearrangement of 8,8-dimethyl- and 6,8,8-trimethyl-naphthalene-1,4,5 8 H -triones 1 and 2 in acetic anhydride as solvent is the subject of a kinetic study.
There was a problem providing the content you requested
Jump to site search. Jump to main content. If you are not the author of this article and disnone wish to reproduce material from it in a third party non-RSC publication you must formally request permission using Copyright Clearance Center. Back to tab navigation. Authors contributing to RSC publications journal articles, books or book chapters do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement fearrangement given with the reproduced material.
Dienone – Wikipedia
For reproduction of material from NJC: If the material has been adapted instead of reproduced from the original RSC publication “Reproduced from” can be substituted with “Adapted from”.
In all cases the Ref.
For reproduction of material from PPS: Dienone—phenol rearrangement mechanism of 8,8-dimethyl- and 6,8,8-trimethyl-naphthalene-1,4,5 8 H -triones in acetic anhydride solution. The effect of temperature in the reaction of 1 and that of the C-6 methyl group of 2 are discussed.
Back to tab navigation Fetching data from CrossRef.
The effects of sulphuric and acetic acids are also investigated. If you are the author of this article you rearrangemennt not need to formally request permission to reproduce figures, diagrams etc.
This may take some time to load. Go to our Instructions for using Copyright Clearance Center page for details.